FOR INDUSTRIAL PHOTOCHEMISTRY
Application Examples: Customised Lab Scale and Pilot Scale Loop Photoreactor System
In synthesis, photochemistry is the method of choice. UV light can
vastly speed up many chemical syntheses – or make them possible in
the first place. Unlike thermal excitation, light-induced reactions
frequently occur at room temperature and are less destructive.
Sensitive molecules remain intact, and there are fewer
by-products.
Our product and competence in preparative photochemistry and
photochemical environmental techniques.
We sell UV-radiation sources and standard photochemical reactors for
immediate use to perform various preparative tasks at laboratory and
pilot levels. UV-radiation sources and corresponding reactors may be
adapted and optimized for specific procedures. ATEX/ IECEx radiation
certification for 2.5 to 40 kW electrical power is available on
request.
In many countries, regulations already govern the testing for
photochemically induced degradation of pharmaceuticals and
cosmetics. Akown delivers appropriate photoreactors. For production
units, we sell entire systems of irradiation, where parts may be
taken from standard programs comprising a variety of dimensions and
types of radiation sources. We neither construct nor sell
photocatalytic reactors for production units, as this task remains
entirely within the domain of competence and responsibility of the
user. However, in cooperation with our partner UV-Technik
Speziallampen GmbH, we offer consulting services based on scientific
and technical expertise.
Furthermore, we offer the possibility to analyse the reactor
geometry of planned or existing production-scale photocatalytic
reactors utilizing professional flow-simulation and physical
radiation data to optimise photochemical processes.
Pilot photocatalytic reactors represent critical intermediate
steps in upscaling all laboratory reactors to an optimized and
well-operating production system. They may also be used to
produce limited amounts of chemical compounds. The UVPI
immersion lamp series has been developed to be retrofitted onto
existing vessels already available in the R&D lab. Furthermore,
optional universal reactors, skid-mounted on a mobile rack, are
available.
Applications:
Specification:
| Sr.No. | Name | Specification |
|---|---|---|
| 01 | UV lamp Type | Medium Pressure Mercury Vapour Lamp |
| 02 | Power | 1.2-5 kW |
| 03 | Max Arc Length | 1000 mm |
| 04 | Mounting Flange | DN 100/120/150 |
| 05 | Cladding Tube 1 MOC | Quartz (UV grade, with special composition) |
| 06 | Cladding Tube 2 MOC | Quartz (UV grade, with special composition), Borosilicate 3.3 |
| 07 | Max Immersion Length | 1200 mm |
| 08 | Water Inlet- Outlet Connections | DN 15 |
| 09 | N2 Inlet- Outlet Connections | 1⁄4 inch Swagelok tube fittings |
| 10 | Power Supply | Ballast VTPS Or Electronic Power supply controller EPSA 80 |
| 11 | Ex-Proof Version | Not Available |
The UVPI SE immersion lamp series represents the most powerful
immersion lamp system available and can be certified up to 40 kW
as per IECEx /ATEX directive for operation in hazardous areas.
Advantageous. Due to the modular construction, UVPI SE immersion
lamps are safe for future demands and can be adapted to changed
process parameters. In addition to the robust and secure design,
an optionally available third protection tube increases the
operational safety of the equipment when necessary.
Applications:
Specification:
| Sr.No. | Name | Specification |
|---|---|---|
| 01 | UV lamp Type | Medium Pressure Mercury Vapour Lamp |
| 02 | Power | 10 – 40 kW |
| 03 | Max Arc Length | 2600 mm |
| 04 | Mounting Flange | DN 250 PN 6/ PN 10 |
| 05 | Cladding Tube 1 MOC | Quartz (UV grade, with special composition) |
| 06 | Cladding Tube 2 MOC | Quartz (UV grade, with special composition) Borosilicate 3.3 |
| 07 | Cladding Tube 3 MOC (Optional) | Quartz (UV grade, with special composition), Borosilicate 3.3 |
| 08 | Max Immersion Length | 3000 mm |
| 09 | Water Inlet- Outlet Connections | DN 15/25 |
| 10 | N2 Inlet- Outlet Connections | Inlet: 1⁄4 inch Swagelok tube fittings Outlet: 1” Male NPT |
| 11 | Power Supply | Ballast VTPS Or Electronic Power supply controller EUV 5 |
| 12 | Ex-Proof Version | Available |
UV medium-pressure lamps are produced as linear lamps as standard. They consist of a sealed discharge tube made of quartz glass. The discharge vessel is filled with noble gases at a low pressure of several millibars. Moreover, UV medium pressure lamps contain a small amount of mercury and dopants, such as iron, gallium, or other elements. During operation, plasma is generated in the lamps, which emits radiation. As a rule, the plasma is excited by establishing a current flow between the electrodes, which are fused or crimped at both ends of the lamp. An electrode-free medium-pressure lamp can be stimulated to light using microwaves. By varying the length, the diameter (Graphic 1), and the filling, UV medium-pressure lamps can be influenced in their performance and adapted to different operating conditions.UV medium-pressure lamps must always be operated on a suitable ballast.
Graphic I: Typical specific performance of UV medium pressure lamps in W/cm light emitting length as a function of Ø
UV medium pressure lamps emit radiation from the UV range to the infrared (Graphic 2).
Graphic 2: Section from the electromagnetic spectrum with its typical classification
A considerable part of the radiation power of a medium pressure lamp
is in the infrared range (Graphic 3).
The lamps therefore
require cooling.
Graphic 3: Distribution of the power of a typical UV medium pressure lamp, Hg type across the spectrum
An automated control system for a UV immersion lamp consists of a Power Control Panel and an Operator Panel, which can be engineered depending on the degree of automation required and the scope for integrating instruments.
An electronic power supply enables stepless and accurate power regulation to the UV lamp. Furthermore, it provides features like measurement, control of process parameters, data logging and transfer, safety interlocks, and a user-friendly interface.